Full Publications for RL Halterman
1. "Stereochemistry at the Migration Terminus in the Base-Induced Rearrangement of alpha-Haloorganoboranes" Midland, M. M.; Zolopa, A. R.; Halterman, R. L. J. Am. Chem. Soc. 1979, 101, 248-249.
2. "Stereoselective Bromination of Allylic Alcohols. A Facile Synthesis of (E)- and (Z)-Bromoepoxides from a Common Starting Material" Midland, M. M.; Halterman, R. L. J. Org. Chem. 1981, 46, 1227-1229.
3. "The Isomerization of Optically-Active Propargyl Alcohols to Terminal Acetylenes" Midland, M. M.; Halterman, R. L.; Brown, C. A.; Yamaichi, A. Tetrahedron Lett. 1981, 24, 4171-4172.
4. "Steric Hindrance to Benzocyclobutene Openings. First Synthesis of a 1,2,3-Tris(trimethyl-silylated) Arene by Cobalt-Catalyzed Alkyne Cyclizations and Application of Fully Coupled Two-Dimensional Chemical Shift Correlations to a Structural Problem" Halterman, R. L.; Nguyen, N. H.; Vollhardt, K. P. C. J. Am. Chem. Soc. 1985, 107, 1379-1387.
5. "Cobalt-Mediated Synthesis of Tricyclic Dienes Incorporating Fused Four-Membered Rings. Unprecedented Rearrangements and Structural Characterization of a Cobalt-Diene Complex by Two-Dimenesional NMR Spectroscopy" Du~ach, E.; Halterman, R. L.; Vollhardt, K. P. C. J. Am. Chem. Soc. 1985, 107, 1664-1671.
6. "Diisopropyl Tartrate Modified (E)-Crotylboronates: Highly Enantioselective Propionate (E)-Enolate Equivalents" Roush, W. R.; Halterman, R. L. J. Am. Chem. Soc. 1986, 108, 294-296.
7. "Practical Synthesis of Two Annelated Optically Active Cyclopentadienes from the Chiral Pool and their Transition Metal Complexes" Halterman, R. L.; Vollhardt, K. P. C. Tetrahedron Lett. 1986, 27, 1461-1464.
8. "Analytical Resolution of Secondary Methyl Ethers by Chiral Complexation Gas Chromatography" Halterman, R. L.; Roush, W. R.; Hoong, L. K. J. Org. Chem. 1987, 52, 1152-1155.
9. "A Designed, Enantiomerically Pure, Fused Cyclopentadienylligand with C2 Symmetry: Synthesis and Use in Enantioselective Titanocene-catalyzed Hydrogenations of Alkenes" Halterman, R. L.; Vollhardt, K. P. C.; Welker, M. E.; Blaser, D.; Boese, R. J. Am. Chem. Soc. 1987, 109, 8105-8107.
10. "Synthesis and Asymmetric Reactivity of Enantiomerically Pure Cyclopentadienylmetal Complexes Deriving from the Chiral Pool" Halterman, R. L.; Vollhardt, K. P. C. Organometallics 1988, 7, 883-892.
11. "First Case of Interannular, Possibly Electronically Transmitted, Asymmetric Induction in an Organometallic Compound" Halterman, R. L.; Vollhardt, K. P. C. Angew. Chem., Int. Ed. Engl. 1988, 27, 553-555.
12. "Synthesis and Crystal Structure of a Chiral C3-Symmetric Monophosphane" Bohm, C.; Davis, W. M.; Halterman, R. L.; Sharpless, K. B. Angew. Chem., Int. Ed. Engl., 1988, 27, 835-837.
13. "Enantioselective Synthesis using Diisopropyl Tartrate Modified (E) and (Z)-Crotylboronates: Reactions with Achiral Aldehydes" Roush, W. R.; Ando, K.; Powers, D. B.; Halterman, R. L.; Palkowitz, A. D. Tetrahedron Lett. 1988, 29, 5579-5582.
14. "Binaphthylcyclopentadiene: A C2-Symmetric Annulated Cyclopentadienyl Ligand with Axial Chirality" Colletti, S. L.; Halterman, R. L. Tetrahedron Lett. 1989, 30, 3513-3156.
15. "Stereoselective Formation of (Cs-Symmetrical p-Allyl)palladium Complexes" Halterman, R. L.; Nimmons, H. L. Organometallics 1990, 9, 273-275.
16. "Asymmetric Synthesis of C2-Symmetric Annulated Bicyclooctylcyclopentadienes" Chen, Z.; Halterman, R. L. Synlett 1990, 103-105.
17. "Diastereoselectivity in the Reduction of Sterically Unbiased 2,2-Diarylcyclo-pentanones" Halterman, R. L.; McEvoy, M. A. J. Am. Chem. Soc. 1990, 112 6990-6995.
18. "Asymmetric Synthesis using Diisopropyl Tartrate Modified (E)- and (Z)-Crotylboronates: Preparation of the Chiral Crotylboronates and Reactions with Achiral Aldehydes" Roush, W. R.; Ando, K.; Powers, D. B.; Palkowitz, A. D.; Halterman, R. L. J. Am. Chem. Soc. 1990, 112, 6339-6347.
19. "Asymmetric Synthesis and Metalation of Binaphthylcyclopentadiene, A C2-Symmetric Chiral Cyclopentadiene" Colletti, S. L.; Halterman, R. L. Organometallics 1991, 10, 3438-3448.
20. "Asymmetric Synthesis and Metalation of C2-Symmetric Annulated Bicyclooctylcyclopentadienes" Chen, Z.; Eriks, K.; Halterman, R. L. Organometallics 1991, 10, 3449-3458.
21. "C2-Symmetric Binaphthyl-Bridged Bisindenylmetal Complexes" Burk, M.; Colletti, S. L., Halterman, R. L. Organometallics 1991, 10, 2998-3000.
22. "Catalytic Asymmetric Epoxidation of Unfunctionalized Alkenes Using the First D4-Symmetric Metalloporphyrin" Halterman, R. L.; Jan, S.-T. J. Org. Chem. 1991, 56, 5253-5254.
23. "Catalytic Asymmetric Oxidation of Sulfides Using a D4-Symmetric Metalloporphyrin" Halterman, R. L.; Nimmons, H. L.Synlett. 1991, 791-794.
24. "Asymmetric Migratory Insertion Reactions of the Chiral Binaphthylcyclcopentadienyliron Complex: (R)-(-)-Binap-CpFe(CO)2CH3" Colletti, S. L.; Halterman, R. L., Organometallics 1992, 11, 980-983.
25. "Evidence of Stereoelectronic Control in Osmylations of Sterically Unbiased 3,3-Diarylcyclopentenes" Halterman, R. L.; McEvoy, M. A. J. Am. Chem. Soc. 1992, 114, 980-985.
26. "Evidence for Stereoelectronic Control in the Epoxidation of Sterically Unbiased Cyclopentenes" Halterman, R. L.; McEvoy, M. A. Tetrahedron Lett. 1992, 33, 753-756.
27. "Asymmetric Epoxdidation of Unfuctionalized Alkenes Using the New C2-symmetrical 1,1'-Binaphthyl-2,2'-dimethylene-Bridged ansa--Bis(1-indenyl)Titanium Dichloride Catalyst" Colletti, S. L.; Halterman, R. L. Tetrahedron Lett. 1992, 33, 1005-1008.
28. "Synthesis and Application of Chiral Cyclopentadienylmetal Complexes" Halterman, R. L. Chem. Rev. 1992, 92, 965-994.
29. "Enantioselective Catalytic Isomerization of an Unfunctionalized Achiral Alkene" Chen, Z.; Halterman, R.L. J. Am. Chem. Soc. 1992, 114, 2276-2277.
30. "Evidence for Stereoelectronic Control in Diels-Alder Cycloadditions of Sterically Unbiased 5,5-Diarylcyclopentadienes" Halterman, R. L.; McCarthy, B. A.; McEvoy, M. A. J. Org. Chem. 1992, 57, 5585-5589.
31. "Bis(Binaphthylcyclopentadienyl)-Derived Metallocene Peroxide Complexes: Catalysts for the Enantioselective Epoxidation of Unfunctionalized Alkenes" Colletti, S. L.; Halterman, R. L. J. Organomet. Chem. 1993, 455, 99-106.
32. "Asymmetric Synthesis of a Sterically Rigid Binaphthyl-Bridged Chiral Metallocene: Asymmetric Catalytic Epoxidation of Unfunctionalized Alkenes" Halterman, R. L.; Ramsey, T. M. Organometallics 1993, 12, 2879-2880.
33. "Enantioselective Ketone Reduction Catalyzed by Chiral Titanocene Complexes" Halterman, R. L.; Ramsey, T. M.; Chen, Z. J. Org. Chem. 1994, 59, 2642-2644.
34. "Electronic Effects of Bis(2-Aryl-4,5,6,7-tetrahydroindenyl)titanocene Dichlorides on the Catalytic Epoxidation of Trans-3-Hexene" Halterman, R. L.; Ramsey, T. M. J. Organomet. Chem. 1994, 465, 175-179.
35. "Chiral Cyclopentane-1,3-Diyl-Bridged ansa-Titanocene Dichlorides" Chen, Z.; Halterman, R. L. Organometallics 1994, 13, 3932-3942.
36. "Synthesis of Camphor-Derived Chiral Cyclopentadienes via the Nazarov Cyclization: Preparation of Chiral Bis(cyclopentadienyl)zirconium and -titanium Dichlorides" Halterman, R. L.; Tretyakov, A. Tetrahedron (Symposium-in-Print) 1995, 51, 4371-4382.
37. “Application of the Double Pauson-Khand Cyclization to the Synthesis of Bis(cyclopentadienes): Preparation of Phenyl-Bridged Bis(tetrahydroindenyl)titanium and Zirconium Dichlorides” Halterman, R. L.; Ramsey, T. M.; Pailes, N. A.; Khan, M. A. J. Organomet. Chem. 1995 497, 43-53.
38. “Crystal Structure of Enantiomerically Pure Bis(Dimethylbicyclopentadienyl)zirconium Dichloride” Halterman, R. L.; Chen, Z. J. Organomet. Chem. 1995, 503, 53-57.
39. “Synthesis of ansa-2,2'-Bis[(4,7-dimethyl-inden-1-yl)methyl]-1,1'-binaphthyl and ansa-2,2'-Bis[(4,5,6,7-tetrahydroinden1-yl)methyl]-1,1'-binaphthyltitanium and -zirconium Dichlorides” Halterman, R. L.; Combs, D.;. Kihega, J. G.; Khan, M. A. J. Organomet. Chem. 1996, 520, 163-170.
40. “Synthesis of D2-Symmetric 5,10,15,20-Tetraarylporphyrins from C2-Symmetric Benzaldehdyes and Achiral Aryldipyrromethanes” Halterman, R. L.; Mei, X. Tetrahedron Lett. 1996, 37, 6291-6294.
40. “Synthesis, Structure Determination and Reactivity of C2-Symmetrical Ethylene-Bridged ansa-Bis(DiMeBCOCp)titanium Dichlorides” Halterman, R. L.; Chen, Z.; Khan, M. A. Organometallics 1996, 15, 3957-3967.
41. “Synthesis and Catalytic Reactivity of Sterically and Electronically Modified D4-Symmetric Metallotetraarylporphyrins” Halterman, R. L.; Jan, S.-T.; Abdulwali, A. H.; Standlee, D. J. Tetrahedron 1997, 11277-11296.
42. “Synthesis and Catalytic Reactivity of D4-Symmetric Dinorbornabenzene-Derived Metallotetraarylporpyrins” Halterman, R. L.; Jan, S.-T.; Nimmons, H. L.; Standlee, D. J.; Khan, M. A. Tetrahedron 1997, 53, 11257-11276.
43. “Preparation of 1,1’-Binaphthyl-2,2’-diyl Bridged ansa-Bis(annulated cyclopentadienyl)titanium and -zirconium Dichloride Complexes” Halterman, R. L.; Ramsey, T. M. J. Organomet. Chem. 1997, 530, 225-234.
44. "Synthesis of C2-Symmetric, Doubly-Bridged Bis(indenyl)titanium and -zirconium Dichlorides” Halterman, R.L.; Tretyakov, A. ; Combs, D.; Chang, J.; Khan, M.Organometallics 1997, 15, 3333-3339.
45. “Conversion of Meso-Alkenes to Chiral Alkenes via Titanocene-Catalyzed Ring-Opening/Ring-Closing Olefin Metathesis” Halterman, R. L.; Ramsey, T. M. J. Organomet. Chem. 1997, 547, 41-48.
46. “Synthesis of Chiral Titanocene and Zirconocene Dichlorides” Halterman, R. L., in Metallocenes, Halterman, R. L.; Togni, A., eds; Wiley-VCH, New York, 1998, 455-544.
47. “The Synthesis of C7-C7’-Ethylene and -Methylene Bridged C2-Symmetric Bis(Indenyl)zirconocene and -titanocene Dichlorides” Halterman, R. L.; Combs, D.; Khan, M. A. Organometallics 1998, 17, 3900-3907.
48. “Synthesis and Structure of [1,2-Bis(1-indenyl)benzene]titanium and -zirconium Dichlorides” Halterman, R. L.; Tretyakov, A.; Khan, M. A. J. Organomet. Chem. 1998, 568, 41-51.
49. “Metalloporphyrin Catalyzed Epoxidations” Halterman, R. L., in Transition Metals in Synthesis , Bolm, C.; Beller, M., eds. Wiley-VCH, Weinheim, 1998.
50. “Asymmetric Hydrogenation of Unfunctionalized Olefins” Halterman, R. L. in Comprehensive Asymmetric Catalysis, Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H., eds. Springer, Heidleberg, 1999, 183-195.
51. “Synthesis and characterisation of 1- and 2-(w-alken-1-yl)indenes, their lithium salts and dichlorozirconium(IV) complexes” Schumann, H.; Karasiak, D. F.; Mühle, S.; Halterman, R. L.; Kaminsky, W.; Weingarten, U. J. Organomet. Chem. 1999, 579, 356.
52. “Efficient Synthesis of 2- and 3-Substituted Indenes from 2-Bromobenzyl Bromide through an Enolate Alkylation / Cr(II)/Ni(II)-Mediated Carbonyl Addition Sequence” Halterman, R. L.; Zhu, J.Tetrahedran Lett. 1999, 40, 7445.
53. Synthesis and Structure of ansa-Metallocene Complexes (M = ZrCl2, TiCl2, YCl, and LuCl) Containing the bis(2-methyl-4,5,6,7-tetrahydroinden-yl)dimethylsilane Ligand Halterman, R. L.; Schumann, H.; Dübner, F. J. Organomet. Chem. 2000, 604, 12-19.
54. "Preparation of 2,5-diisopropylcyclohexane-1,4-bis(indenyl)titanium Dichloride and 2,5-diisopropylcyclohexane-1,4-bis(tetrahydroindenyl)titanium Dichloride and Their Comparison as Catalysts for the Enantioselective Pinacol Coupling of Benzaldehyde” Halterman, R. L.; Zhu, C.; Chen, Z.; Dunlap, M. L.; Khan, M. A.; Nicholas, K.M. Organometallics 2000, 19, 324-329.
55. Synthesis, Characterization and Polymerization Properties of Bis(2-menthylindenyl)zirconium Dichloride and Bis(2-menthyl-4,7-dimethylindenyl)zirconium Dichloride Halterman, R. L.; Fahey, D.R.; Bailly, E.F.; Dockter, D. W.; Stenzel, O.; Shipman, J. L.; Khan, M. A.; Dechert, S.; Schumann, H. Organometallics 2000, 19, 3824-3829.
56. “Synthesis, Characterization and Polymerization Properties of Isopropylidene(5-3-Neomenthylcyclopentadienyl)( 5-fluorenyl)zirconium Dichloride” Halterman, R.L.; Marin, V.P.; Khan, M. A.; Fahey, D. F.; Dockter, D. W. Journal of Organometallic Chemistry 2001, 625, 154-159.
57. "Synthesis and Characterization of (-)-1-Menthyl-4,7-Dimethylindene and its Main Group Metal Complexes of Lithium, Sodium, Potassium and Tin" Schumann, H.; Stenzel, O.; Girgsdies, F.; Halterman, R. L. Organometallics 2001, 20, 1743-1751
58. "Menthyl Functionalized Chiral Nonracemic Bis(indenyl) Complexes of Zirconium, Iron, Nickel, and Ruthenium" Schumann, H.; Stenzel, O.; Dechert, S.; Halterman, R. L. Organometallics 2001, 20, 1983-1991
59. "Menthyl Functionalized Chiral Nonracemic Monoindenyl Complexes of Rhodium, Iridium, Cobalt, and Molybdenum" Schumann, H.; Stenzel, O.; Dechert, S.; Girgsdies, F.; Halterman, R. L. Organometallics 2001, 20, 2215-2225.
60. “Synthesis, Structure and Catalytic Activity of some new chiral (–)-2-Menthylindenyl- and (–)-2-Menthyl-4,7-dimethylindenyl Rhodium Complexes.” Schumann, H.; Stenzel, O.; Dechert, S.; Girgsdies, F.; Blum, J.; Gelman, D.; R. L. Halterman,R.L. Eur. J. Inorg. Chem., 2002 211-219
61. “Preparation of Chiral Annulated Indenes Derived from Nopinone, Verbenone and Menthone” Halterman, R.L. and Crow, L.D. Tetrahedron Letters 2003, 44, 2907-2909
62. “Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds” Halterman, R.L. in Comprehensive Asymmetric Catalysis, Supplement 2, Jacobsen, E.N.; Pfaltz, A.; Yamamoto, H., Eds. Springer, Berlin, 2004, pages 1-6.
Patent
1. “Olefin Polymerization” US patent issued Jan, 1998, Filed July 17, 1996 by Phillips Petroleum Company with R.L. Halterman and T.M.Ramsey (OU) and D. R. Fahey and G. Hawley (Phillips) as coauthors. With 18 international filings.
Books/Manual
1. Organic Chemistry Laboratory Manual, 4th ed. Halterman, R. L., Morvant, M. C.; Phillips, M., RonJon Publishers, Texas, 1998.
2. Metallocenes, Halterman, R. L.; Togni, A., eds; Wiley-VCH, Weinheim 1998